Fiverr Revenue Card and Payoneer Card are the same thing. Have you read this? http://support.fiverr.com/hc/en-us/articles/206272908-Setting-up-Your-Fiverr-Revenue-Card It explains the process of applying for the card.
Activation fee for Payoneer is $30 if you register independently, or $24 (I think) if you register through a referral link, and it’s charged automatically when you have funds on your Payoneer Card. After that, yearly fee of the same amount will be taken from your Payoneer account when you have funds available, either monthly or yearly, depending on the card. As for other charges, if you go to Payoneer’s website you’ll find everything explained and all fees listed nicely.
If there’s something else you’d like to know, I’d be happy to help.